Issue 18, 2008
From the journal:

Chemical Communications

Asymmetric synthesis of β-lactams using chiral-memory effect on photochemical γ-hydrogen abstraction by thiocarbonyl group†

Masami Sakamoto,*a   Hiroya Kawanishi,a   Takashi Minoa  and  Tsutomu Fujitaa  

* Corresponding authors

a Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba, Japan
E-mail: sakamotom@faculty.chiba-u.jp
Fax: 81 43 290 3401
Tel: 81 43 290 3387

Abstract

Optically active β-lactams were synthesized via photochemical intramolecular γ-hydrogen abstraction reaction of thioimides involving a highly-controlled chiral-memory effect.

Graphical abstract: Asymmetric synthesis of β-lactams using chiral-memory effect on photochemical γ-hydrogen abstraction by thiocarbonyl group

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Article information

DOI
https://doi.org/10.1039/B801524D
Article type
Communication
Submitted
28 Jan 2008
Accepted
28 Feb 2008
First published
26 Mar 2008

Chem. Commun., 2008, 2132-2133

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Asymmetric synthesis of β-lactams using chiral-memory effect on photochemical γ-hydrogen abstraction by thiocarbonyl group

M. Sakamoto, H. Kawanishi, T. Mino and T. Fujita, Chem. Commun., 2008, 2132 DOI: 10.1039/B801524D

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