Issue 15, 2008
From the journal:

Chemical Communications

Nucleophilicities and carbon basicities of DBU and DBN†‡

M. Baidyaa  and  Herbert Mayr*a  

* Corresponding authors

a Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13 (Haus F), 81377 München, Germany
E-mail: herbert.mayr@cup.lmu.de
Fax: +49-89-218077717

Abstract

The nucleophilicity and Lewis basicity of DBU and DBN toward Csp2 centers have been measured: nucleophilicities increase in the series DMAP < DBU < DBN < DABCO while Lewis basicities are DABCO < DMAP < DBU < DBN.

Graphical abstract: Nucleophilicities and carbon basicities of DBU and DBN

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Article information

DOI
https://doi.org/10.1039/B801811A
Article type
Communication
Submitted
07 Feb 2008
Accepted
19 Feb 2008
First published
13 Mar 2008

Chem. Commun., 2008, 1792-1794

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Nucleophilicities and carbon basicities of DBU and DBN

M. Baidya and H. Mayr, Chem. Commun., 2008, 1792 DOI: 10.1039/B801811A

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