Issue 35, 2008
From the journal:

Chemical Communications

Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding†

D. Bridget Williams,a   Werner Kaminsky,b   James M. Mayer*a  and  Karen I. Goldberg*a  

* Corresponding authors

a The Center for Enabling New Technologies through Catalysis (CENTC), Department of Chemistry, University of Washington, Box 351700, Seattle, Washington, USA

b X-Ray Crystallographic Facility, Department of Chemistry, University of Washington, Box 351700, Seattle, Washington, USA

Abstract

The reaction of molecular oxygen with iridium pincer hydride complexes, (tBuPCP)Ir(H)(X) [tBuPCP = κ3-C6H3(CH2PtBu2)2, X = Ph, H, CCPh], results in O2 induced reductive elimination and formation of the novel dioxygen complexes (tBuPCP)Ir(O2)n [n = 1 (7), 2 (6)].

Graphical abstract: Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding

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Article information

DOI
https://doi.org/10.1039/B802739K
Article type
Communication
Submitted
18 Feb 2008
Accepted
10 Jun 2008
First published
04 Aug 2008

Chem. Commun., 2008, 4195-4197

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Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding

D. Bridget Williams, W. Kaminsky, J. M. Mayer and K. I. Goldberg, Chem. Commun., 2008, 4195 DOI: 10.1039/B802739K

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