Issue 27, 2008
From the journal:

Chemical Communications

N-Dealkylation of aliphatic amines and selective synthesis of monoalkylated aryl amines†

Dirk Hollmann,a   Sebastian Bähn,a   Annegret Tillacka  and  Matthias Beller*a  

* Corresponding authors

a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, Rostock, Germany
E-mail: matthias.beller@catalysis.de
Tel: +49 381 1281 113

Abstract

Highly selective alkyl transfer processes of mono-, di- and trialkyl amines in the presence of the Shvo catalyst have been realized; in addition, a general method for N-alkylation of aniline with di- and trialkyl amines is presented.

Graphical abstract: N-Dealkylation of aliphatic amines and selective synthesis of monoalkylated aryl amines

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Article information

DOI
https://doi.org/10.1039/B803114B
Article type
Communication
Submitted
25 Feb 2008
Accepted
07 Apr 2008
First published
08 May 2008

Chem. Commun., 2008, 3199-3201

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N-Dealkylation of aliphatic amines and selective synthesis of monoalkylated aryl amines

D. Hollmann, S. Bähn, A. Tillack and M. Beller, Chem. Commun., 2008, 3199 DOI: 10.1039/B803114B

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