Issue 28, 2008
From the journal:

Chemical Communications

Self-association of the N-methyl benzotellurodiazolylium cation: implications for the generation of super-heavy atom radicals†

Maarit Risto,ab   Robert W. Reed,a   Craig M. Robertson,a   Raija Oilunkaniemi,b   Risto S. Laitinen*b  and  Richard T. Oakley*a  

* Corresponding authors

a Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada
E-mail: oakley@uwaterloo.ca

b Department of Chemistry, University of Oulu, P.O. Box 3000, Finland
E-mail: risto.laitinen@oulu.fi

Abstract

The N-methyl benzotellurodiazolylium cation self-associates in the solid state via short (2.471(3) Å) 4-center Te⋯N′ intermolecular contacts; electrochemical data and the results of DFT calculations suggest that the dimers persist in solution.

Graphical abstract: Self-association of the N-methyl benzotellurodiazolylium cation: implications for the generation of super-heavy atom radicals

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Article information

DOI
https://doi.org/10.1039/B803159B
Article type
Communication
Submitted
28 Feb 2008
Accepted
17 Apr 2008
First published
15 May 2008

Chem. Commun., 2008, 3278-3280

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Self-association of the N-methyl benzotellurodiazolylium cation: implications for the generation of super-heavy atom radicals

M. Risto, R. W. Reed, C. M. Robertson, R. Oilunkaniemi, R. S. Laitinen and R. T. Oakley, Chem. Commun., 2008, 3278 DOI: 10.1039/B803159B

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