Issue 27, 2008
From the journal:

Chemical Communications

Rhodium-catalyzed enantioselective desymmetrization of bicyclic hydrazines with alkynylboronic esters†

Stefano Crotti,a   Ferruccio Bertolini,a   Franco Macchiaa  and  Mauro Pineschi*a  

* Corresponding authors

a Dipartimento di Chimica Bioorganica e Biofarmacia, Università di Pisa, Via Bonanno 33, Pisa, Italy
E-mail: pineschi@farm.unipi.it
Fax: +390502219660

Abstract

The first successful asymmetric transfer of rhodium–alkynyl species to symmetrical strained alkenes has been realized starting from bicyclic hydrazines and alkynylboronic esters.

Graphical abstract: Rhodium-catalyzed enantioselective desymmetrization of bicyclic hydrazines with alkynylboronic esters

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Article information

DOI
https://doi.org/10.1039/B803693D
Article type
Communication
Submitted
04 Mar 2008
Accepted
07 Apr 2008
First published
08 May 2008

Chem. Commun., 2008, 3127-3129

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Rhodium-catalyzed enantioselective desymmetrization of bicyclic hydrazines with alkynylboronic esters

S. Crotti, F. Bertolini, F. Macchia and M. Pineschi, Chem. Commun., 2008, 3127 DOI: 10.1039/B803693D

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