Issue 10, 2008
From the journal:

CrystEngComm

Two 3D hybrid networks of mog and bcu topology constructed with copper(I/I,II) halides and N,N′-spacers†

Hong-Qing Hao,a   Jing Wang,a   Wen-Ting Liua  and  Ming-Liang Tong*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: tongml@mail.sysu.edu.cn

Abstract

Hydrothermal reactions of freshly synthesized Cu(OH)2, 4,4′-bipyridine/1,3-bis(4-pyridyl)propane, dilute HCl/isophthalic acid yielded two 3D metal–organic hybrid networks with CuI2(μ4-Cl) chain or tetrameric mixed-valence CuI2CuII2(μ3-Cl)2cluster as secondary building units. They have chiral moganite-type (mog) topology with both square planar and tetrahedral nodes and decorated body-centered cubic (bcu) topological net with 8-connected CuI2CuII2(μ3-Cl)2cluster as node.

Graphical abstract: Two 3D hybrid networks of mog and bcu topology constructed with copper(I/I,II) halides and N,N′-spacers

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Article information

DOI
https://doi.org/10.1039/B803728K
Article type
Paper
Submitted
04 Mar 2008
Accepted
16 Jul 2008
First published
05 Aug 2008

CrystEngComm, 2008,10, 1454-1459

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Two 3D hybrid networks of mog and bcu topology constructed with copper(I/I,II) halides and N,N′-spacers

H. Hao, J. Wang, W. Liu and M. Tong, CrystEngComm, 2008, 10, 1454 DOI: 10.1039/B803728K

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