Issue 22, 2008
From the journal:

Chemical Communications

Bio-inspired oxidation of methane in water catalyzed by N-bridged diiron phthalocyanine complex†

Alexander B. Sorokin,*a   Evgeny V. Kudrika  and  Denis Bouchub  

* Corresponding authors

a Institut de Recherches sur la Catalyse et l’Environnement de Lyon (IRCELYON), UMR 5256, CNRS-Université Lyon, 2, av. A. Einstein, 69626 Villeurbanne Cedex, France
E-mail: alexander.sorokin@ircelyon.univ-lyon1.fr
Fax: +33 47244539
Tel: +33 472445337

b Université Lyon 1, UMR 5246, Centre Commun de Spectroscopie de Masse, 43, bd du 11 Novembre, 69622 Villeurbanne Cedex, France

Abstract

A stable μ-nitrido diiron phthalocyanine activates H2O2 to oxidize CH4 in water at 25–60 °C to methanol, formaldehyde and formic acid as evidenced using 13C and 18O labelling.

Graphical abstract: Bio-inspired oxidation of methane in water catalyzed by N-bridged diiron phthalocyanine complex

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Article information

DOI
https://doi.org/10.1039/B804405H
Article type
Communication
Submitted
14 Mar 2008
Accepted
15 Apr 2008
First published
02 May 2008

Chem. Commun., 2008, 2562-2564

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Bio-inspired oxidation of methane in water catalyzed by N-bridged diiron phthalocyanine complex

A. B. Sorokin, E. V. Kudrik and D. Bouchu, Chem. Commun., 2008, 2562 DOI: 10.1039/B804405H

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