Synthesis, structure and magnetic properties of linear heterobimetallic trinuclear Mn2Ln (Ln = Eu, Gd, Dy) complexes

Vadapalli Chandrasekhar; Balasubramanian Murugesa Pandian; Ramamoorthy Boomishankar; Alexander Steiner; Rodolphe Clérac

doi:10.1039/B804435J

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Synthesis, structure and magnetic properties of linear heterobimetallic trinuclear Mn₂Ln (Ln = Eu, Gd, Dy) complexes†

Vadapalli Chandrasekhar,*^a Balasubramanian Murugesa Pandian,^a Ramamoorthy Boomishankar,^b Alexander Steiner^b and Rodolphe Clérac*^c

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* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208 016, India
E-mail: vc@iitk.ac.in
Fax: +91 512 259 0007
Tel: +91 512 259 7259

^b Department of Chemistry, University of Liverpool, Liverpool, U.K,

^c Université Bordeaux 1; CNRS, Centre de Recherche Paul Pascal-UPR8641, 115 avenue du Dr Albert Schweitzer, 33600 Pessac, France
E-mail: clerac@crpp-bordeaux.cnrs.fr

Abstract

The reaction of (S)P[N(CH₃)N [double bond, length as m-dash] CH-C₆H₃-2-OH-3-OCH₃]₃ with a Mn^II salt followed by a Ln^III salt (Ln = Eu, Gd and Dy), afforded linear heterometallic complexes [L₂Mn₂Ln]⁺ that showed interesting magnetic properties.

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Article information

DOI: https://doi.org/10.1039/B804435J
Article type: Communication
Submitted: 14 Mar 2008
Accepted: 18 Jul 2008
First published: 12 Aug 2008

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Dalton Trans., 2008, 5143-5145

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Synthesis, structure and magnetic properties of linear heterobimetallic trinuclear Mn₂Ln (Ln = Eu, Gd, Dy) complexes

V. Chandrasekhar, B. M. Pandian, R. Boomishankar, A. Steiner and R. Clérac, Dalton Trans., 2008, 5143 DOI: 10.1039/B804435J

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Dalton Transactions