How are tris(triazolyl)borate ligands electronically different from tris(pyrazolyl)borate ligands? A study of (TtztBu,Me)CuCO [TtztBu,Me = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate]

Elizabeth T. Papish; Trisha M. Donahue; Kirsten R. Wells; Glenn P. A. Yap

doi:10.1039/B804951C

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How are tris(triazolyl)borateligands electronically different from tris(pyrazolyl)borateligands? A study of (Ttz^tBu,Me)CuCO [Ttz^tBu,Me = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate]†

Elizabeth T. Papish,*^a Trisha M. Donahue,^b Kirsten R. Wells^b and Glenn P. A. Yap^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, Drexel University, 3141 Chestnut St., Philadelphia, PA, USA
E-mail: elizabeth.papish@drexel.edu

^b Department of Chemistry, Salisbury University, 1101 Camden Ave., Salisbury, Maryland, USA

^c Department of Chemistry, University of Delaware, Newark, Delaware, USA

Abstract

(Ttz^tBu,Me)CuCO [Ttz^tBu,Me = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate] was prepared and fully characterized to test whether the Ttz^tBu,Me ligand, which is sterically similar to Tp^tBu,Me is electronically different; Ttz^tBu,Me is a weaker electron donor and (Ttz^tBu,Me)CuCO is water stable and has a propensity to form hydrogen bonds.

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Supplementary files

Crystal structure data TXT (22K)

Article information

DOI: https://doi.org/10.1039/B804951C
Article type: Communication
Submitted: 25 Mar 2008
Accepted: 26 Mar 2008
First published: 15 Apr 2008

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Dalton Trans., 2008, 2923-2925

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How are tris(triazolyl)borate ligands electronically different from tris(pyrazolyl)borate ligands? A study of (Ttz^tBu,Me)CuCO [Ttz^tBu,Me = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate]

E. T. Papish, T. M. Donahue, K. R. Wells and G. P. A. Yap, Dalton Trans., 2008, 2923 DOI: 10.1039/B804951C

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Dalton Transactions