Issue 25, 2008

Rh(ii)-catalyzed skeletal reorganization of enynes involving selective cleavage of C–C triple bonds

Abstract

Treatment of enynes with a catalytic amount of Rh(II) complex results in skeletal reorganization to give cis-configured 1-vinylcycloalkenes, the formation of which occurs via double cleavage of both C–C double and C–C triple bonds.

Graphical abstract: Rh(ii)-catalyzed skeletal reorganization of enynes involving selective cleavage of C–C triple bonds

Supplementary files

Article information

Article type
Communication
Submitted
26 Mar 2008
Accepted
21 Apr 2008
First published
29 May 2008

Chem. Commun., 2008, 2906-2907

Rh(II)-catalyzed skeletal reorganization of enynes involving selective cleavage of C–C triple bonds

K. Ota and N. Chatani, Chem. Commun., 2008, 2906 DOI: 10.1039/B805100C

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