Issue 40, 2008
From the journal:

Dalton Transactions

Evidence of flexibility in the nanoporous iron(iii) carboxylate MIL-89†

C. Serre,*a   S. Surblé,a   C. Mellot-Draznieks,ab   Y. Filinchukc  and  G. Féreyad  

* Corresponding authors

a Institut Lavoisier, UMR CNRS 8180, Université de Versailles, 45, Avenue des Etats-Unis, 78035 Versailles Cedex, France
E-mail: serre@chimie.uvsq.fr

b Royal Institution of Great Britain, 21, Albemarle Street, London, UK

c SNBL at ESRF, rue Jules Horowitz, 38043 Grenoble, France

d Institut Universitaire de France, 78035 Versailles, France

Abstract

The very large expansion upon adsorption of liquids, up to 160% in cell volume, has been observed in the iron(III) trans,trans muconate MIL-89 [(MIL = Material Institut Lavoisier]. The structure of lutidine-containing MIL-89 (lutidine = 2,6-dimethylpyridine) has been determined using X-ray powder diffraction and computer simulations. Finally, the consequences of adsorption of various polar and apolar liquids have been evaluated using ex situsynchrotron X-ray powder diffraction data and reveals that the swelling behavior of MIL-89 is selective but slightly different from the MIL-88 analogues.

Graphical abstract: Evidence of flexibility in the nanoporous iron(iii) carboxylate MIL-89

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B805408H
Article type
Paper
Submitted
01 Apr 2008
Accepted
13 Jun 2008
First published
30 Jul 2008

Dalton Trans., 2008, 5462-5464

Permissions

Request permissions

Evidence of flexibility in the nanoporous iron(III) carboxylate MIL-89

C. Serre, S. Surblé, C. Mellot-Draznieks, Y. Filinchuk and G. Férey, Dalton Trans., 2008, 5462 DOI: 10.1039/B805408H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements