Issue 35, 2008
From the journal:

Chemical Communications

Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane

Youn-Sang Bae,a   Omar K. Farha,b   Alexander M. Spokoyny,b   Chad A. Mirkin,b   Joseph T. Huppb  and  Randall Q. Snurr*a  

* Corresponding authors

a Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, USA
E-mail: snurr@northwestern.edu
Fax: 1-847-467-1018
Tel: 1-847-467-2977

b Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, USA

Abstract

Separation of CO2/CH4 mixtures was studied in carborane-based metal–organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.

Graphical abstract: Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane

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Article information

DOI
https://doi.org/10.1039/B805785K
Article type
Communication
Submitted
07 Apr 2008
Accepted
30 May 2008
First published
15 Jul 2008

Chem. Commun., 2008, 4135-4137

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Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane

Y. Bae, O. K. Farha, A. M. Spokoyny, C. A. Mirkin, J. T. Hupp and R. Q. Snurr, Chem. Commun., 2008, 4135 DOI: 10.1039/B805785K

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