Issue 32, 2008
From the journal:

Chemical Communications

Enantioselective rhodium-catalysed 1,4-additions of 2-heteroarylzinc donors using Me-DUPHOS†

Jérôme Le Nôtre,a   Joseph C. Allena  and  Christopher G. Frost*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: c.g.frost@bath.ac.uk
Fax: 44 01225 386231
Tel: 44 01225 386142

Abstract

The enantioselective 1,4-addition of 2-(substituted)thienylzinc and 2-furanylzinc reagents has been achieved (up to 99 : 1 er) using a complex derived from [Rh(C2H4)2Cl]2 and Me-DUPHOS.

Graphical abstract: Enantioselective rhodium-catalysed 1,4-additions of 2-heteroarylzinc donors using Me-DUPHOS

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Article information

DOI
https://doi.org/10.1039/B806098C
Article type
Communication
Submitted
10 Apr 2008
Accepted
07 May 2008
First published
23 Jun 2008

Chem. Commun., 2008, 3795-3797

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Enantioselective rhodium-catalysed 1,4-additions of 2-heteroarylzinc donors using Me-DUPHOS

J. Le Nôtre, J. C. Allen and C. G. Frost, Chem. Commun., 2008, 3795 DOI: 10.1039/B806098C

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