Issue 36, 2008
From the journal:

Chemical Communications

Proton-coupled electron transfer from a luminescent excited state†

Jonathan C. Freys,a   Gérald Bernardinellib  and  Oliver S. Wenger*a  

* Corresponding authors

a Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai Ernest-Ansermet, Geneva 4, Switzerland
E-mail: oliver.wenger@unige.ch
Fax: +41(0)22 379 60 69
Tel: +41(0)22 379 60 51

b Laboratory of X-ray Crystallography, University of Geneva, 24 quai Ernest-Ansermet, Geneva 4, Switzerland

Abstract

A luminescent cationic iridium complex with a 2,2′-biimidazole ligand forms hydrogen-bonded 1 : 1 adducts with benzoate anions; photoexcitation of the metal complex in presence of 3,5-dinitrobenzoate triggers a proton-coupled electron transfer.

Graphical abstract: Proton-coupled electron transfer from a luminescent excited state

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Article information

DOI
https://doi.org/10.1039/B806175K
Article type
Communication
Submitted
11 Apr 2008
Accepted
20 May 2008
First published
15 Jul 2008

Chem. Commun., 2008, 4267-4269

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Proton-coupled electron transfer from a luminescent excited state

J. C. Freys, G. Bernardinelli and O. S. Wenger, Chem. Commun., 2008, 4267 DOI: 10.1039/B806175K

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