Issue 45, 2008
From the journal:

Chemical Communications

Rhodium-catalysed anomalous dimerization of styrenes involving the cleavage of the ortho C–H bond†

Mamoru Tobisu,*a   Isao Hyodo,b   Masahiro Onoeb  and  Naoto Chatani*b  

* Corresponding authors

a Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: tobisu@chem.eng.osaka-u.ac.jp
Fax: +81 6 6879 7396
Tel: +81 6 6879 7395

b Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: chatani@chem.eng.osaka-u.ac.jp
Fax: +81 6 6879 7396
Tel: +81 6 6879 7397

Abstract

The dimerization of styrene derivatives in the presence of a rhodium catalyst proceeds to give stilbene derivatives, in which the ortho C–H bond of styrenes is cleaved and functionalized.

Graphical abstract: Rhodium-catalysed anomalous dimerization of styrenes involving the cleavage of the ortho C–H bond

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Article information

DOI
https://doi.org/10.1039/B806285D
Article type
Communication
Submitted
14 Apr 2008
Accepted
20 Aug 2008
First published
10 Oct 2008

Chem. Commun., 2008, 6013-6015

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Rhodium-catalysed anomalous dimerization of styrenes involving the cleavage of the ortho C–H bond

M. Tobisu, I. Hyodo, M. Onoe and N. Chatani, Chem. Commun., 2008, 6013 DOI: 10.1039/B806285D

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