Issue 10, 2008
From the journal:

CrystEngComm

A self-assembled tetrameric water cluster stabilized by the hexachlororhenate(IV) anion and diprotonated 2,2′-biimidazole: X-ray structure and magnetic properties †

J. Martínez-Lillo,*ab   D. Armentano,b   G. De Munno,*b   N. Marino,b   F. Lloret,a   M. Julvea  and  J. Fausa  

* Corresponding authors

a Departamento de Química Inorgánica/Instituto de Ciencia Molecular, Facultad de Química de la Universidad de Valencia, Dr. Moliner 50, Burjassot, Valencia, Spain
E-mail: juan.faus@uv.es, lillo@uv.es

b Dipartimento di Chimica, Università della Calabria, via P. Bucci 14/c, Rende, Cosenza, Italy
E-mail: demunno@unical.it

Abstract

A self-assembled tetrameric water cluster stabilized by [ReCl6]2− anions and [H4biim]2+ cations occurs in the new compound [H4biim][ReCl6]·4H2O, which exhibits a weak ferromagnetic coupling between the Re(IV) centers through an unusual ReIV–Cl⋯(H2O)⋯Cl–ReIV pathway.

Graphical abstract: A self-assembled tetrameric water cluster stabilized by the hexachlororhenate(IV) anion and diprotonated 2,2′-biimidazole: X-ray structure and magnetic properties

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B806729E
Article type
Communication
Submitted
21 Apr 2008
Accepted
04 Jul 2008
First published
29 Jul 2008

CrystEngComm, 2008,10, 1284-1287

Permissions

Request permissions

A self-assembled tetrameric water cluster stabilized by the hexachlororhenate(IV) anion and diprotonated 2,2′-biimidazole: X-ray structure and magnetic properties

J. Martínez-Lillo, D. Armentano, G. De Munno, N. Marino, F. Lloret, M. Julve and J. Faus, CrystEngComm, 2008, 10, 1284 DOI: 10.1039/B806729E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements