Issue 36, 2008

Ni(ii)-catalyzed enantioselective Nazarov cyclizations

Abstract

Nazarov cyclizations are catalyzed by a dicationic Ni(II) complex containing the chiral tridentate phosphine Pigiphos; the catalyst exerts a high degree of torquoselectivity and affords the products in up to 88% ee.

Graphical abstract: Ni(ii)-catalyzed enantioselective Nazarov cyclizations

Supplementary files

Article information

Article type
Communication
Submitted
23 Apr 2008
Accepted
03 Jun 2008
First published
17 Jul 2008

Chem. Commun., 2008, 4315-4317

Ni(II)-catalyzed enantioselective Nazarov cyclizations

I. Walz and A. Togni, Chem. Commun., 2008, 4315 DOI: 10.1039/B806870D

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