Issue 32, 2008

Abnormal coordination of Arduengo's carbene upon reaction with M3(CO)12 (M = Ru, Os)

Abstract

The first examples of abnormal coordination of Ardeungo’s carbene, 1,3-bis-adamantylimidazol-2-ylidene, have been isolated and structurally characterised following reaction of the free carbene with the trinuclear clusters M3(CO)12 (M = Ru, Os).

Graphical abstract: Abnormal coordination of Arduengo's carbene upon reaction with M3(CO)12 (M = Ru, Os)

Supplementary files

Article information

Article type
Communication
Submitted
09 May 2008
Accepted
06 Jun 2008
First published
19 Jun 2008

Dalton Trans., 2008, 4209-4211

Abnormal coordination of Arduengo's carbene upon reaction with M3(CO)12 (M = Ru, Os)

M. R. Crittall, C. E. Ellul, M. F. Mahon, O. Saker and M. K. Whittlesey, Dalton Trans., 2008, 4209 DOI: 10.1039/B807923D

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