Issue 17, 2008
From the journal:

Organic & Biomolecular Chemistry

Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis–Hillman reactions†

Satish Garre,a   Erica Parker,a   Bukuo Ni*a  and  Allan D. Headley*a  

* Corresponding authors

a Department of Chemistry, Texas A & M-University-Commerce, Commerce, TX, USA
E-mail: bukuo_ni@tamu-commerce.edu, allan_headley@tamu-commerce.edu

Abstract

Three novel chiral ionic liquids (CILs) containing two chiral centers in the side chain bonded to the 2-position of the imidazolium cation and different anions have been synthesized, characterized and used as chiral solvents for asymmetric Baylis–Hillman (BH) reactions; good yields and fair enantioselectivities were obtained.

Graphical abstract: Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis–Hillman reactions

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Article information

DOI
https://doi.org/10.1039/B808502A
Article type
Communication
Submitted
20 May 2008
Accepted
11 Jul 2008
First published
21 Jul 2008

Org. Biomol. Chem., 2008,6, 3041-3043

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Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis–Hillman reactions

S. Garre, E. Parker, B. Ni and A. D. Headley, Org. Biomol. Chem., 2008, 6, 3041 DOI: 10.1039/B808502A

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