Issue 31, 2008
From the journal:

Dalton Transactions

A ladder based on paddlewheel diruthenium(ii, ii) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase†

Natsuko Motokawa,a   Tomomi Oyama,a   Satoshi Matsunaga,a   Hitoshi Miyasaka,*a   Kunihisa Sugimoto,b   Masahiro Yamashita,a   Nazario Lopezc  and  Kim R. Dunbarc  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi, Japan
E-mail: miyasaka@agnus.chem.tohoku.ac.jp
Fax: +81-22-795-6548
Tel: +81-22-795-6545

b X-Ray Research Laboratory, Rigaku Co. Ltd., 3-9-12 Matsubara-cho, Akishima, Tokyo, Japan

c Department of Chemistry, Texas A&M University, PO Box 30012, College Station, TX, USA

Abstract

The slow diffusion reaction of [Ru2(O2CCF3)4(THF)2] with TCNQ in CH2Cl2/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru2] rails and TCNQ rungs in a 2 : 1 ratio.

Graphical abstract: A ladder based on paddlewheel diruthenium(ii, ii) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase

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Article information

DOI
https://doi.org/10.1039/B808503J
Article type
Communication
Submitted
20 May 2008
Accepted
16 Jun 2008
First published
01 Jul 2008

Dalton Trans., 2008, 4099-4102

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A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase

N. Motokawa, T. Oyama, S. Matsunaga, H. Miyasaka, K. Sugimoto, M. Yamashita, N. Lopez and K. R. Dunbar, Dalton Trans., 2008, 4099 DOI: 10.1039/B808503J

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