Issue 34, 2008
From the journal:

Chemical Communications

Substituent effects on the aromatic edge-to-face interaction†‡

Felix Raoul Fischer,a   W. Bernd Schweizera  and  François Diederich*a  

* Corresponding authors

a Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH-Hönggerberg, HCI, CH-8093 Zurich, Switzerland
E-mail: diederich@org.chem.ethz.ch
Fax: +41 44-632-1109

Abstract

Substituent effects on the folding equilibrium of molecular torsion balances are rationalised on the basis of changes in the electrostatic interactions, the exchange repulsion, and the dispersive contributions to the interaction free enthalpy.

Graphical abstract: Substituent effects on the aromatic edge-to-face interaction

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Article information

DOI
https://doi.org/10.1039/B809058K
Article type
Communication
Submitted
28 May 2008
Accepted
30 Jun 2008
First published
24 Jul 2008

Chem. Commun., 2008, 4031-4033

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Substituent effects on the aromatic edge-to-face interaction

F. R. Fischer, W. B. Schweizer and F. Diederich, Chem. Commun., 2008, 4031 DOI: 10.1039/B809058K

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