Issue 41, 2008

Copper-catalyzed asymmetric allylic substitution with aryl and ethylGrignard reagents

Abstract

Phenyl- and ethyl-magnesium bromides undergo regioselective asymmetric allylic substitution with high enantioselectivity under the catalysis of chiral amidophosphane–copper(I) complexes.

Graphical abstract: Copper-catalyzed asymmetric allylic substitution with aryl and ethylGrignard reagents

Supplementary files

Article information

Article type
Communication
Submitted
29 May 2008
Accepted
16 Jul 2008
First published
09 Sep 2008

Chem. Commun., 2008, 5140-5142

Copper-catalyzed asymmetric allylic substitution with aryl and ethylGrignard reagents

K. B. Selim, K. Yamada and K. Tomioka, Chem. Commun., 2008, 5140 DOI: 10.1039/B809140D

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