Response: Why had long-lived electron-transfer states of donor-substituted 10-methylacridinium ions been overlooked? Formation of the dimer radical cations detected in the near-IR region

Shunichi Fukuzumi; Hiroaki Kotani; Kei Ohkubo

doi:10.1039/B809264H

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Response: Why had long-lived electron-transfer states of donor-substituted 10-methylacridinium ions been overlooked? Formation of the dimer radical cations detected in the near-IR region†

Shunichi Fukuzumi,*^a Hiroaki Kotani^a and Kei Ohkubo^a

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^a Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency (JST), Suita, Osaka, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: +81 (0)6 6879 7370
Tel: +81 (0)6 6879 7368

Abstract

Photoexcitation of an acetonitrile solution of the 9-(1-naphthyl)-10-methylacridinium ion results in formation of the electron-transfer state that forms the long-lived dimer radical cation with the acridinium ion, which was clearly detected as the transient absorption spectrum in the near-IR region.

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DOI: https://doi.org/10.1039/B809264H
Article type: Comment
Submitted: 02 Jun 2008
Accepted: 25 Jun 2008
First published: 08 Jul 2008

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Phys. Chem. Chem. Phys., 2008,10, 5159-5162

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Response: Why had long-lived electron-transfer states of donor-substituted 10-methylacridinium ions been overlooked? Formation of the dimer radical cations detected in the near-IR region

S. Fukuzumi, H. Kotani and K. Ohkubo, Phys. Chem. Chem. Phys., 2008, 10, 5159 DOI: 10.1039/B809264H

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Physical Chemistry Chemical Physics

Response: Why had long-lived electron-transfer states of donor-substituted 10-methylacridinium ions been overlooked? Formation of the dimer radical cations detected in the near-IR region†

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Response: Why had long-lived electron-transfer states of donor-substituted 10-methylacridinium ions been overlooked? Formation of the dimer radical cations detected in the near-IR region

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