Tuning the shape of nanoparticles to control their catalytic properties: selective hydrogenation of 1,3-butadiene on Pd/Al2O3

Laurent Piccolo; Ana Valcarcel; Marta Bausach; Cécile Thomazeau; Denis Uzio; Gilles Berhault

doi:10.1039/B809651A

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Tuning the shape of nanoparticles to control their catalytic properties: selective hydrogenation of 1,3-butadiene on Pd/Al₂O₃†

Laurent Piccolo,*^a Ana Valcarcel,^a Marta Bausach,^a Cécile Thomazeau,^b Denis Uzio^b and Gilles Berhault^a

Author affiliations

* Corresponding authors

^a IRCELYON, UMR 5256 CNRS and Université Claude Bernard-Lyon 1, 2 Avenue Albert Einstein, Villeurbanne Cedex, France
E-mail: laurent.piccolo@ircelyon.univ-lyon1.fr

^b IFP-Lyon, BP 3, Vernaison, France

Abstract

Shape-controlled Pd nanoparticles supported on powder alumina are more efficient for selective butadiene hydrogenation to butene when they exhibit high fractions of (111) facets.

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Supplementary files

Details on catalyst preparation, experimental setup andsample characterization PDF (1337K)

Article information

DOI: https://doi.org/10.1039/B809651A
Article type: Communication
Submitted: 09 Jun 2008
Accepted: 26 Jun 2008
First published: 24 Jul 2008

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Phys. Chem. Chem. Phys., 2008,10, 5504-5506

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Tuning the shape of nanoparticles to control their catalytic properties: selective hydrogenation of 1,3-butadiene on Pd/Al₂O₃

L. Piccolo, A. Valcarcel, M. Bausach, C. Thomazeau, D. Uzio and G. Berhault, Phys. Chem. Chem. Phys., 2008, 10, 5504 DOI: 10.1039/B809651A

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