Issue 39, 2008
From the journal:

Chemical Communications

Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system†

Bao Zhanga  and  Andrew G. H. Wee*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Regina, Regina, Saskatchewan, Canada
E-mail: andrew.wee@uregina.ca

Abstract

The intramolecular metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(TMS)methyl diazoamides proceeds with high conformational control and chemoselectivity to give cyclopropyl derivatives, which rearrange to β-carboline products.

Graphical abstract: Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

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Article information

DOI
https://doi.org/10.1039/B809890E
Article type
Communication
Submitted
11 Jun 2008
Accepted
11 Jul 2008
First published
28 Aug 2008

Chem. Commun., 2008, 4837-4839

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Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

B. Zhang and A. G. H. Wee, Chem. Commun., 2008, 4837 DOI: 10.1039/B809890E

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