Issue 44, 2008

Reversible dynamic isomerism change in the solid state, from Bi4I16clusters to BiI4 1D chains in l-cystine based hybrids: templating effect of cations in iodobismuthate network formation

Abstract

The dehydration of a iodobismuthate hybrid built up from Bi4I16clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI4 chains and 1D helical molecular chains, highlighting the templating effect of cations in the formation of iodobismuthate network.

Graphical abstract: Reversible dynamic isomerism change in the solid state, from Bi4I16clusters to BiI4 1D chains in l-cystine based hybrids: templating effect of cations in iodobismuthate network formation

Supplementary files

Article information

Article type
Communication
Submitted
22 Jul 2008
Accepted
08 Sep 2008
First published
01 Oct 2008

Chem. Commun., 2008, 5743-5745

Reversible dynamic isomerism change in the solid state, from Bi4I16clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation

W. Bi and N. Mercier, Chem. Commun., 2008, 5743 DOI: 10.1039/B812588K

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