Issue 44, 2008

Mononuclear Ti[triple bond, length as m-dash]N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

Abstract

The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2], in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].

Graphical abstract: Mononuclear Ti [[triple bond, length as m-dash]] N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

Supplementary files

Article information

Article type
Communication
Submitted
25 Jul 2008
Accepted
15 Sep 2008
First published
08 Oct 2008

Chem. Commun., 2008, 5776-5778

Mononuclear Ti[triple bond, length as m-dash]N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

A. Fuller, W. Clegg, R. W. Harrington, D. L. Hughes and S. J. Lancaster, Chem. Commun., 2008, 5776 DOI: 10.1039/B812785A

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