Issue 44, 2008
From the journal:

Chemical Communications

Deuterated polymer gels for measuring anisotropic NMR parameters with strongly reduced artefacts†

Grit Kummerlöwe,a   Sebastian Knör,a   Andreas O. Frank,a   Thomas Paululat,b   Horst Kesslera  and  Burkhard Luy*a  

* Corresponding authors

a Center of Integrated Protein Science at the Department of Chemistry, Technische Universität München, Lichtenbergstr. 4, Garching, Germany
E-mail: Burkhard.Luy@ch.tum.de
Tel: +49 89 28913275

b Organic Chemistry II, University of Siegen, Adolf-Reichwein-Str. 2, Siegen, Germany

Abstract

Perdeuterated poly(styrene) is introduced as an almost artefact-free and arbitrarily scalable alignment medium for measuring residual dipolar couplings and other anisotropic NMR parameters; the spectral quality achievable in this new medium is demonstrated for HSQC spectra leading to the conformational analysis of staurosporine and homonuclear TOCSY-type experiments.

Graphical abstract: Deuterated polymer gels for measuring anisotropic NMR parameters with strongly reduced artefacts

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Article information

DOI
https://doi.org/10.1039/B812905C
Article type
Communication
Submitted
25 Jul 2008
Accepted
03 Sep 2008
First published
06 Oct 2008

Chem. Commun., 2008, 5722-5724

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Deuterated polymer gels for measuring anisotropic NMR parameters with strongly reduced artefacts

G. Kummerlöwe, S. Knör, A. O. Frank, T. Paululat, H. Kessler and B. Luy, Chem. Commun., 2008, 5722 DOI: 10.1039/B812905C

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