Issue 22, 2008

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

Abstract

Alkene difunctionalization, the addition of two functional groups across a double bond, exemplifies a class of reactions with significant synthetic potential. This emerging area examines recent developments of palladium-catalyzed difunctionalization reactions, with a focus on mechanistic strategies that allow for functionalization of a common palladium alkyl intermediate.

Graphical abstract: Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

Article information

Article type
Emerging Area
Submitted
31 Jul 2008
Accepted
22 Aug 2008
First published
09 Oct 2008

Org. Biomol. Chem., 2008,6, 4083-4088

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

K. H. Jensen and M. S. Sigman, Org. Biomol. Chem., 2008, 6, 4083 DOI: 10.1039/B813246A

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