Issue 47, 2008
From the journal:

Chemical Communications

A cavitand with a fluorous rim acts as an amine receptor†

Richard J. Hooley,‡a   Per Restorpa  and  Julius Rebek Jr*a  

* Corresponding authors

a The Skaggs Institute for Chemical Biology and the Department of Chemistry, The Scripps Research Institute, La Jolla, USA
E-mail: jrebek@scripps.edu
Fax: +1 858.784.2876
Tel: +1 858.784.2250

Abstract

A deep cavitand featuring eight trifluoroacetyl groups attached to the open end has been synthesized; these functions provide new chemical surfaces and constrict access to the cavitand, yet increase the rates of guest exchange.

Graphical abstract: A cavitand with a fluorous rim acts as an amine receptor

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Article information

DOI
https://doi.org/10.1039/B814069C
Article type
Communication
Submitted
13 Aug 2008
Accepted
13 Oct 2008
First published
06 Nov 2008

Chem. Commun., 2008, 6291-6293

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A cavitand with a fluorous rim acts as an amine receptor

R. J. Hooley, P. Restorp and J. Rebek Jr, Chem. Commun., 2008, 6291 DOI: 10.1039/B814069C

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