Issue 11, 2009
From the journal:

Physical Chemistry Chemical Physics

Selective observation of the two oxygen atoms at different sites in the carboxyl group (–COOH) of liquid acetic acid

Takashi Tokushima,*a   Yuka Horikawa,ab   Yoshihisa Harada,acd   Osamu Takahashi,e   Atsunari Hirayab  and  Shik Shinaf  

* Corresponding authors

a RIKEN/SPring-8, Sayo-cho, Sayo, Hyogo, Japan
E-mail: toku@spring8.or.jp
Fax: +81 791 58 2934
Tel: +81 791 58 2933

b Department of Physics, Hiroshima University, Higashi-Hiroshima, Japan

c Department of Applied Chemistry, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan

d JST, CREST, Kawaguchi, Saitama, Japan

e Department of Chemistry, Hiroshima University, Higashi-Hiroshima, Japan

f Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba, Japan

Abstract

A study of the excitation energy dependence of resonant X-ray emission spectra across the O1s absorption edge in combination with X-ray absorption spectroscopy and density functional theory reveals the site-specific valence electronic structure of liquid acetic acid under ambient conditions.

Graphical abstract: Selective observation of the two oxygen atoms at different sites in the carboxyl group (–COOH) of liquid acetic acid

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Article information

DOI
https://doi.org/10.1039/B818812B
Article type
Communication
Submitted
27 Oct 2008
Accepted
13 Jan 2009
First published
02 Feb 2009

Phys. Chem. Chem. Phys., 2009,11, 1679-1682

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Selective observation of the two oxygen atoms at different sites in the carboxyl group (–COOH) of liquid acetic acid

T. Tokushima, Y. Horikawa, Y. Harada, O. Takahashi, A. Hiraya and S. Shin, Phys. Chem. Chem. Phys., 2009, 11, 1679 DOI: 10.1039/B818812B

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