Issue 12, 2009
From the journal:

Chemical Communications

Electrically-controlled near-infrared chiroptical switching of enantiomeric dinuclear ruthenium complexes†

Duo Li,a   Zhi Yuan Wang*a  and  Dongge Mab  

* Corresponding authors

a Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, Canada
E-mail: wayne_wang@carleton.ca
Fax: +1 613 520 2316
Tel: +1 613 520 2600 ext. 2713

b State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Abstract

Enantiomerically pure dinuclear ruthenium complexes with 1,2-dicarbonylhydrazide as a bridging ligand are optically active in the visible and near infrared spectral regions depending on the oxidation states of the metal centers and are useful as an electrochemically driven near infrared chiroptical switch.

Graphical abstract: Electrically-controlled near-infrared chiroptical switching of enantiomeric dinuclear ruthenium complexes

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Article information

DOI
https://doi.org/10.1039/B819270G
Article type
Communication
Submitted
30 Oct 2008
Accepted
22 Jan 2009
First published
20 Feb 2009

Chem. Commun., 2009, 1529-1531

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Electrically-controlled near-infrared chiroptical switching of enantiomeric dinuclear ruthenium complexes

D. Li, Z. Y. Wang and D. Ma, Chem. Commun., 2009, 1529 DOI: 10.1039/B819270G

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