Issue 9, 2009

Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3

Abstract

Mono- and bis-phosphinoferrocenes are shown to react as frustrated Lewis pairs (FLPs) to effect nucleophilicaromatic substitution on B(C6F5)3 and/or activate H2 to form ferrocenylphosphonium borates.

Graphical abstract: Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3

Supplementary files

Article information

Article type
Communication
Submitted
03 Nov 2008
Accepted
10 Dec 2008
First published
12 Jan 2009

Chem. Commun., 2009, 1118-1120

Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3

A. Ramos, A. J. Lough and D. W. Stephan, Chem. Commun., 2009, 1118 DOI: 10.1039/B819525K

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