Issue 13, 2009

A facile access to [60]fullerene-fused δ-lactones: unexpected reaction pathway of benzenediazonium-2-carboxylates controlled by organic bases

Abstract

The reaction of [60]fullerene with anthranilic acids and isoamyl nitrite in the presence of triethylamine unexpectedly afforded [60]fullerene-fused δ-lactones, which would be difficult to be prepared by other known methods; the organic base played a crucial role in the unusual reaction pathway.

Graphical abstract: A facile access to [60]fullerene-fused δ-lactones: unexpected reaction pathway of benzenediazonium-2-carboxylates controlled by organic bases

Supplementary files

Article information

Article type
Communication
Submitted
14 Nov 2008
Accepted
08 Jan 2009
First published
04 Feb 2009

Chem. Commun., 2009, 1769-1771

A facile access to [60]fullerene-fused δ-lactones: unexpected reaction pathway of benzenediazonium-2-carboxylates controlled by organic bases

G. Wang and B. Zhu, Chem. Commun., 2009, 1769 DOI: 10.1039/B820395D

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