Issue 13, 2009
From the journal:

Chemical Communications

Catalytic nitrene transfer from an imidoiron(iii) complex to form carbodiimides and isocyanates†

Ryan E. Cowley,a   Nathan A. Eckert,a   Jérôme Elhaïka  and  Patrick L. Holland*a  

* Corresponding authors

a Department of Chemistry, University of Rochester, Rochester, USA
E-mail: holland@chem.rochester.edu

Abstract

The metastable iron(III) imido species LtBuFeNAd catalyzes transfer of the nitrene fragment NAd from an organic azide to isocyanides or CO, forming unsymmetrical carbodiimides or isocyanates.

Graphical abstract: Catalytic nitrene transfer from an imidoiron(iii) complex to form carbodiimides and isocyanates

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DOI
https://doi.org/10.1039/B820620A
Article type
Communication
Submitted
18 Nov 2008
Accepted
21 Jan 2009
First published
17 Feb 2009

Chem. Commun., 2009, 1760-1762

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Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates

R. E. Cowley, N. A. Eckert, J. Elhaïk and P. L. Holland, Chem. Commun., 2009, 1760 DOI: 10.1039/B820620A

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