Issue 7, 2009
From the journal:

Dalton Transactions

The influence of tetrahydrofuran on the structures and reactivities of lithium organo-amidocuprates†

Roberta Bomparola,a   Robert P. Davies,*a   Stefan Hornauera  and  Andrew J. P. Whitea  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: r.davies@imperial.ac.uk
Fax: +44 870 1300438
Tel: +44 207 5945754

Abstract

The organo-amidocuprate [Cu2Li2Mes2(N(CH2Ph)2)2] is solvated by thf to yield the monomeric contact ion pair complex [MesCuN(CH2Ph)2.Li(thf)3] in which the Li cation is bound to the amido nitrogen; this behaviour differs significantly from that observed in diorganocuprates which favour solvent separate ion pairs.

Graphical abstract: The influence of tetrahydrofuran on the structures and reactivities of lithium organo-amidocuprates

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Article information

DOI
https://doi.org/10.1039/B821206F
Article type
Communication
Submitted
04 Nov 2008
Accepted
04 Dec 2008
First published
18 Dec 2008

Dalton Trans., 2009, 1104-1106

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The influence of tetrahydrofuran on the structures and reactivities of lithium organo-amidocuprates

R. Bomparola, R. P. Davies, S. Hornauer and A. J. P. White, Dalton Trans., 2009, 1104 DOI: 10.1039/B821206F

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