Issue 16, 2009
From the journal:

Dalton Transactions

Hydride–bromide exchange at an NHC—a new route to brominated alanes and gallanes†

Sean G. Alexander,b   Marcus L. Cole,*a   Samantha K. Furfaria  and  Marc Klothb  

* Corresponding authors

a School of Chemistry, University of New South Wales, Sydney, NSW, Australia
E-mail: m.cole@unsw.edu.au
Fax: +61 2 93856141
Tel: +61 2 93854678

b School of Chemistry and Physics, University of Adelaide, Adelaide, SA, Australia

Abstract

The reaction of [MH3(Quinuclidine)] (M = Al or Ga) with an air stable dibrominated N-heterocyclic carbene (NHC) affords the hydride–bromide exchange product [MBr2H(NHC)].

Graphical abstract: Hydride–bromide exchange at an NHC—a new route to brominated alanes and gallanes

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Article information

DOI
https://doi.org/10.1039/B821367D
Article type
Communication
Submitted
28 Nov 2008
Accepted
11 Feb 2009
First published
18 Feb 2009

Dalton Trans., 2009, 2909-2911

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Hydride–bromide exchange at an NHC—a new route to brominated alanes and gallanes

S. G. Alexander, M. L. Cole, S. K. Furfari and M. Kloth, Dalton Trans., 2009, 2909 DOI: 10.1039/B821367D

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