Issue 26, 2009

IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings

Abstract

Five metal–organic frameworks (MOFs) based on the same three-dimensional gallium terephthalate network (IM-19) are described, and an incommensurate structure (for the as-synthesized form) as well as two remarkable guest-free polymorphs (open and closed) are highlighted.

Graphical abstract: IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings

Supplementary files

Article information

Article type
Communication
Submitted
11 Dec 2008
Accepted
01 Apr 2009
First published
24 Apr 2009

Phys. Chem. Chem. Phys., 2009,11, 5241-5245

IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings

G. Chaplais, A. Simon-Masseron, F. Porcher, C. Lecomte, D. Bazer-Bachi, N. Bats and J. Patarin, Phys. Chem. Chem. Phys., 2009, 11, 5241 DOI: 10.1039/B822163D

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