Oxoammonium salt/NaClO2: an expedient, catalytic system for one-pot oxidation of primary alcohols to carboxylic acids with broad substrate applicability

Masatoshi Shibuya; Takahisa Sato; Masaki Tomizawa; Yoshiharu Iwabuchi

doi:10.1039/B822944A

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Oxoammonium salt/NaClO₂: an expedient, catalytic system for one-pot oxidation of primary alcohols to carboxylic acids with broad substrate applicability†

Masatoshi Shibuya,^a Takahisa Sato,‡^a Masaki Tomizawa^a and Yoshiharu Iwabuchi*^a

Author affiliations

* Corresponding authors

^a Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3 Aobayama, Sendai, Japan
E-mail: iwabuchi@mail.pharm.tohoku.ac.jp
Fax: +81-22-795-6845
Tel: +81-22-795-6846

Abstract

A facile, green, one-pot oxidation of primary alcohols to carboxylic acids with broad substrate applicability has been developed by employing an expedient catalytic system consisting of 1-Me-AZADO⁺X⁻/NaClO₂.

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Supplementary files

Experimental procedures and selected spectra for newcompounds PDF (6043K)

Article information

DOI: https://doi.org/10.1039/B822944A
Article type: Communication
Submitted: 19 Dec 2008
Accepted: 16 Jan 2009
First published: 11 Feb 2009

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Chem. Commun., 2009, 1739-1741

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Oxoammonium salt/NaClO₂: an expedient, catalytic system for one-pot oxidation of primary alcohols to carboxylic acids with broad substrate applicability

M. Shibuya, T. Sato, M. Tomizawa and Y. Iwabuchi, Chem. Commun., 2009, 1739 DOI: 10.1039/B822944A

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