Issue 11, 2009
From the journal:

Dalton Transactions

Ferrimagnetic [CoII3(μ3-OH)2(RCO2)4] chains embedded in a laminar hybrid material exhibiting single-chain magnet behaviour†

Sheng Hu,ac   Lei Yun,a   Yan-Zhen Zheng,*b   Yan-Hua Lan,b   Annie. K. Powellb  and  Ming-Liang Tong*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, P. R. China
E-mail: tongml@mail.sysu.edu.cn

b Institut für Anorganische Chemie de Universität Karlsruhe, Engesserstrasse Geb. 30.45, Karlsruhe, Germany

c Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, P. R. China

Abstract

The ligand, benzophenone-2,4′-dicarboxylate, was used as a polytopic linker and magnetic separator to bridge the inorganic hydroxide-bridged cobat(II) chain motifs into a laminar inorganic–organic hybrid materials with nearest inter-chain Co(II)⋯Co(II) distance of ca. 8.14 Å, which exhibits single-chain magnet behaviour.

Graphical abstract: Ferrimagnetic [CoII3(μ3-OH)2(RCO2)4] chains embedded in a laminar hybrid material exhibiting single-chain magnet behaviour

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Article information

DOI
https://doi.org/10.1039/B901163N
Article type
Communication
Submitted
19 Jan 2009
Accepted
29 Jan 2009
First published
07 Feb 2009

Dalton Trans., 2009, 1897-1900

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Ferrimagnetic [CoII3(μ3-OH)2(RCO2)4] chains embedded in a laminar hybrid material exhibiting single-chain magnet behaviour

S. Hu, L. Yun, Y. Zheng, Y. Lan, Annie. K. Powell and M. Tong, Dalton Trans., 2009, 1897 DOI: 10.1039/B901163N

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