Issue 25, 2009
From the journal:

Chemical Communications

Luminescence vapochromic properties of a platinum(ii) complex with 5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine†

Jun Ni,a   Li-Yi Zhang,a   Hui-Min Wena  and  Zhong-Ning Chen*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: czn@fjirsm.ac.cn

Abstract

A platinum(II) complex of 5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine displays unusually reversible colour and luminescence changes when exposed to specific organic vapours, correlated well with Pt⋯Pt distances as well as π–π and C–H⋯(C[triple bond, length as m-dash]C) interactions in the stacking of square-planar platinum(II) moieties.

Graphical abstract: Luminescence vapochromic properties of a platinum(ii) complex with 5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine

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Article information

DOI
https://doi.org/10.1039/B901248F
Article type
Communication
Submitted
21 Jan 2009
Accepted
29 Apr 2009
First published
19 May 2009

Chem. Commun., 2009, 3801-3803

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Luminescence vapochromic properties of a platinum(II) complex with 5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine

J. Ni, L. Zhang, H. Wen and Z. Chen, Chem. Commun., 2009, 3801 DOI: 10.1039/B901248F

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