Issue 22, 2009

{Ge9R3Cr(CO)5} and {Ge9R3Cr(CO)3}: a metalloid cluster (Ge9R3) as a flexible ligand in coordination chemistry [R = Si(SiMe3)3]

Abstract

The reactions of the metalloid cluster {Ge9[Si(SiMe3)3]3} with Cr(CO)5COE (COE = cyclooctene) and Cr(CO)3(CH3CN)3 lead to the new cluster compounds {Ge9[Si(SiMe3)3]3Cr(CO)5} and {Ge9[Si(SiMe3)3]3Cr(CO)3}, whose structural and electronic properties are presented.

Graphical abstract: {Ge9R3Cr(CO)5}− and {Ge9R3Cr(CO)3}−: a metalloid cluster (Ge9R3−) as a flexible ligand in coordination chemistry [R = Si(SiMe3)3]

Supplementary files

Article information

Article type
Communication
Submitted
28 Jan 2009
Accepted
07 Apr 2009
First published
05 May 2009

Chem. Commun., 2009, 3208-3210

{Ge9R3Cr(CO)5} and {Ge9R3Cr(CO)3}: a metalloid cluster (Ge9R3) as a flexible ligand in coordination chemistry [R = Si(SiMe3)3]

C. Schenk and A. Schnepf, Chem. Commun., 2009, 3208 DOI: 10.1039/B901870K

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