Issue 23, 2009
From the journal:

Chemical Communications

Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand†

Gaelle Dupouy,a   Mathieu Marchivie,a   Smail Triki,*a   Jean Sala-Pala,a   Carlos J. Gómez-García,b   Sébastien Pillet,c   Claude Lecomtec  and  Jean-François Létardd  

* Corresponding authors

a UMR CNRS 6521, Université de Bretagne Occidentale, BP 809, Brest Cedex, France
E-mail: triki@univ-brest.fr
Fax: +33 298017001
Tel: +33 298016146

b Instituto de Ciencia Molecular. Parque Científico. Universidad de Valencia, Paterna, Valencia, Spain

c LCM3B, Nancy-Université, CNRS, Boulevard des Aiguillettes, B.P. 239, Nancy, France

d ICMCB, CNRS, Université Bordeaux 1, 87 Av. Doc. A. Schweitzer, Pessac, France

Abstract

A new polymeric approach, based on cyanocarbanion ligands, for the design of spin crossover (SCO) compounds led us to the compound [Fe(abpt)2(tcpd)] (1) (tcpd2− = (C[C(CN)2]3)2−, abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) which has been characterised as the first SCO molecular chain involving a cyanocarbanion as bridging ligand.

Graphical abstract: Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand

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Article information

DOI
https://doi.org/10.1039/B902339A
Article type
Communication
Submitted
03 Feb 2009
Accepted
27 Mar 2009
First published
29 Apr 2009

Chem. Commun., 2009, 3404-3406

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Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand

G. Dupouy, M. Marchivie, S. Triki, J. Sala-Pala, C. J. Gómez-García, S. Pillet, C. Lecomte and J. Létard, Chem. Commun., 2009, 3404 DOI: 10.1039/B902339A

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