Issue 10, 2009
From the journal:

New Journal of Chemistry

Chiral ionic liquids derived from isosorbide: synthesis, properties and applications in asymmetric synthesis

Olivier Nguyen Van Buu,a   Audrey Aupoix,a   Nhung Doan Thi Honga  and  Giang Vo-Thanh*a  

* Corresponding authors

a Laboratoire de Catalyse Moléculaire, Institut de Chimie Moléculaire et des Matériaux d’Orsay, UMR 8182, Université Paris-Sud 11, 91405 Orsay Cedex, France
E-mail: gvothanh@icmo.u-psud.fr

Abstract

A novel class of chiral ammonium and imidazolium-based ionic liquids has been designed and synthesized using isosorbide as a biorenewable substrate. These chiral ionic liquids were found to catalyze the aza Diels–Alder reaction to give good yields and moderate diastereoselectivitives.

Graphical abstract: Chiral ionic liquids derived from isosorbide: synthesis, properties and applications in asymmetric synthesis

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Article information

DOI
https://doi.org/10.1039/B902956G
Article type
Paper
Submitted
12 Feb 2009
Accepted
22 Jun 2009
First published
23 Jul 2009

New J. Chem., 2009,33, 2060-2072

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Chiral ionic liquids derived from isosorbide: synthesis, properties and applications in asymmetric synthesis

O. N. Van Buu, A. Aupoix, N. D. T. Hong and G. Vo-Thanh, New J. Chem., 2009, 33, 2060 DOI: 10.1039/B902956G

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