Issue 15, 2009
From the journal:

Organic & Biomolecular Chemistry

Remarkable increase in basicity associated with supramolecular gelation†

Francisco Rodríguez-Llansola,a   Beatriu Escuder*a  and  Juan F. Miravet*a  

* Corresponding authors

a Departament de Química Inorgànica i Orgànica, Universitat Jaume I, 12071 Castelló, Spain
E-mail: escuder@qio.uji.es, miravet@qio.uji.es
Fax: (+34) 964728214

Abstract

L-Proline derivatives which are able to form supramolecular gels show an amazing basicity increase in the aggregated (gel) state as compared to solution. As a result they behave as enantioselective catalysts for the aldol reaction in solution but produce a base-catalyzed aldol racemisation in the gel state.

Graphical abstract: Remarkable increase in basicity associated with supramolecular gelation

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Article information

DOI
https://doi.org/10.1039/B904523F
Article type
Paper
Submitted
05 Mar 2009
Accepted
08 May 2009
First published
08 Jun 2009

Org. Biomol. Chem., 2009,7, 3091-3094

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Remarkable increase in basicity associated with supramolecular gelation

F. Rodríguez-Llansola, B. Escuder and J. F. Miravet, Org. Biomol. Chem., 2009, 7, 3091 DOI: 10.1039/B904523F

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