Issue 19, 2009

μ2-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism

Abstract

The first carbon monoxide-releasing molecules (CO-RMs) based on μ2-alkyne dicobalt(0)hexacarbonyl complexes are reported. The alkyne substituents significantly affect the rate of CO-release, cytotoxicity and cell viability. Mechanistic studies provide insight into the CO-RM activation pathways.

Graphical abstract: μ2-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism

Supplementary files

Article information

Article type
Communication
Submitted
05 Mar 2009
Accepted
16 Mar 2009
First published
26 Mar 2009

Dalton Trans., 2009, 3653-3656

μ2-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism

A. J. Atkin, S. Williams, P. Sawle, R. Motterlini, J. M. Lynam and I. J. S. Fairlamb, Dalton Trans., 2009, 3653 DOI: 10.1039/B904627P

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