Issue 8, 2009
From the journal:

CrystEngComm

Crystal engineering by eliminating weak hydrogen bonding sites in phenolic polyene nonlinear optical crystals†

O-Pil Kwon,*a   Mojca Jazbinsek,*b   Hoseop Yun,c   Jung-In Seo,d   Ji-Youn Seo,a   Seong-Ji Kwon,b   Yoon Sup Leed  and  Peter Günterb  

* Corresponding authors

a Department of Molecular Science and Technology, Ajou University, Suwon, Korea
E-mail: opilkwon@ajou.ac.kr
Fax: +82 31 219 1610

b Nonlinear Optics Laboratory, ETH Zurich, Zurich, Switzerland
E-mail: nlo@phys.ethz.ch

c Division of Energy Systems Research and Department of Chemistry, Ajou University, Suwon, Korea

d Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon, Korea

Abstract

A new acentric polyene crystal OH3 with a large macroscopic second-order optical nonlinearity with optimal chromophore orientation for electro-optics and THz-wave applications has been developed by crystal engineering, eliminating weak CH⋯NC hydrogen-bonding sites, but still retaining strong OH⋯NC hydrogen-bonding sites of the analogue OH1 crystals.

Graphical abstract: Crystal engineering by eliminating weak hydrogen bonding sites in phenolic polyene nonlinear optical crystals

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Article information

DOI
https://doi.org/10.1039/B904688G
Article type
Communication
Submitted
06 Mar 2009
Accepted
07 May 2009
First published
27 May 2009

CrystEngComm, 2009,11, 1541-1544

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Crystal engineering by eliminating weak hydrogen bonding sites in phenolic polyene nonlinear optical crystals

O. Kwon, M. Jazbinsek, H. Yun, J. Seo, J. Seo, S. Kwon, Y. S. Lee and P. Günter, CrystEngComm, 2009, 11, 1541 DOI: 10.1039/B904688G

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