Issue 20, 2009

Synthesis and structure of [{N(CH2CH2NSiMe3)3}URe(η5-C5H5)2]: a heterobimetallic complex with an unsupported uranium–rhenium bond

Abstract

The first structurally authenticated molecular uranium–transition metal bond is reported; DFT studies show σ- and π-components in the U–Re bond and this is the first time that the latter component has been reported in an unsupported f-element–transition metal bond.

Graphical abstract: Synthesis and structure of [{N(CH2CH2NSiMe3)3}URe(η5-C5H5)2]: a heterobimetallic complex with an unsupported uranium–rhenium bond

Supplementary files

Article information

Article type
Communication
Submitted
01 Apr 2009
Accepted
14 Apr 2009
First published
24 Apr 2009

Chem. Commun., 2009, 2851-2853

Synthesis and structure of [{N(CH2CH2NSiMe3)3}URe(η5-C5H5)2]: a heterobimetallic complex with an unsupported uranium–rhenium bond

B. M. Gardner, J. McMaster, W. Lewis and S. T. Liddle, Chem. Commun., 2009, 2851 DOI: 10.1039/B906554G

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