Issue 26, 2009

Highly efficient oxidation of sulfides with hydrogen peroxide catalyzed by [SeO4{WO(O2)2}2]2−

Abstract

By using the selenium-containing dinuclear peroxotungstate at 0.005–0.1 mol%, various kinds of sulfides could be converted into the corresponding sulfoxides or sulfones in excellent yields with one or two equivalents of H2O2 with respect to the sulfide, respectively.

Graphical abstract: Highly efficient oxidation of sulfides with hydrogen peroxide catalyzed by [SeO4{WO(O2)2}2]2−

Supplementary files

Article information

Article type
Communication
Submitted
21 Apr 2009
Accepted
11 May 2009
First published
02 Jun 2009

Chem. Commun., 2009, 3958-3960

Highly efficient oxidation of sulfides with hydrogen peroxide catalyzed by [SeO4{WO(O2)2}2]2−

K. Kamata, T. Hirano and N. Mizuno, Chem. Commun., 2009, 3958 DOI: 10.1039/B907952A

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